You should have mentioned this in your OP as it's important information considering your request. Very few use 16k Atari machines anymore. Luckily, I was able to spot some "free space" in the Defender Cartridge ROMs to add the functionality that you requested. Hopefully, you are able to load and enjoy this "hacked" Cartridge ROM. Let me know how it goes.
DEFENDER Cartridge[EFPatched-Joybutton2-Uses-Smartbombs].rom